Thats well beyond my 40 year old, chem 101 knowledge too! I was reading about other brands of nute that also say they are PH stable, so thats a real thing I guess.
The problem, as you say, is in the EC you need to run to keep things stable. From what Atomizer said, if you are spraying enough volume of nutes to recirculate, then higher EC is no problem, but at very low flow rates, the droplets can evaporate enough to multiply the concentration in the droplets.
If a 50 micron droplet evaporates 1/2 its volume in the time it takes to get from the nozzle to the roots, then the EC will be double. Smaller droplets will loose volume to evaporation faster than larger ones, so some droplets may triple in EC as they evaporate. He recomends running at 1/4 to 1/2 normal EC levels if you have low enough flow rates and small enough droplets.
I am seeing some evidence of that in my system. The inlet PPM probe always runs a little lower than the outlet probe - even though there is essentially no plant action going on to this point. How much seems to vary from day to day, so Im assuming that the relative humidity and temperature around the root chamber are factors. The only thing that I can imagine causing that is evaporation of the droplets after they leave the nozzles and before the water gets to the collection chamber.
Im running an EC in the rez of about .5 and the runoff has been just slightly above that. So far the difference has not been more than 10% at the most though. That would have to be an average, so Im thinking that smaller droplets are going up a lot more in EC than the larger droplets. The big ones are probably not changing all that much, while the smaller ones are changing a lot more.
Im using the same Normally Closed solenoids you are. It was a mechanical failure of some kind. All the solenoids are driven by the same timer, with separate solenoids for each nozzle. Only the one nozzle that failed stayed open, and it stayed open with the power shut down completely.
I am constantly surprised by these plants. Thats one of the things I Like about this growing stuff
I think Im finally getting close to dialing things in enough to start relaxing - unless I just jinxed it!. Im currently running at .3 sec ON and 33 sec OFF and everyone seems happy.
Ive been playing between .3 and 1.0 seconds ON and 30 to 120 seconds off. One of the tricks is that if you let things dry out even a little too much, you have to go heavy for them to recover. Then you have to start over dialing it back down slooooowly.
I really should have gone with just seeds or just new clones. They seem to want different wetness levels, so Im kind of balancing things in between for now. It may be another week before the clone starts to show roots.