I have humic acid in powder but it’s hydrophobic, and just floats around on the surface of the water.
The vinegar will keep the ph down for about 18 hours then it starts to climb again, and after a couple of days is back up around 7.5 to 8.
There is nowhere I know that sells sulphuric acid around here, I wish they did, I have several batteries I could bring back to life.