I don’t believe a leaf would ever be considered less than 100% humid unless it was severely under-watered such that the leaves were essentially drying out.
The vapor pressure of the leaf is always considered to be the saturation vapor pressure because we’re evaluating the conditions just inside the leaf stomates. Due to the proximity to unprotected internal leaf tissue, the small air volumes inside of the stomatal cavities are considered to be saturated. So once we measure the leaf temperature, we can use an equation to determine the saturation vapor pressure of the air inside the stomatal cavities.[1]
It’s an interesting question though. I’ll look around for any references where the leaf vapor pressure is considered less than the vapor saturation pressure. There are conditions when things go wrong such as too much light where the leaf temperature ends up something higher than the ambient (typically it’s slightly less if the leaf is has normal transpiration – think evaporative cooling).
Typically your target is to adjust the environmental conditions to achieve the desired VPD to optimize the plant transpiration rates (and hence optimize the nutrient uptake).