I thought about that for calcium supplementation, but haven’t played with it much. My concern is the higher pH of kalkwasser would possibly raise the pH in the res too much. Aragonite on its own, aka coral rubble, will raise the pH on its own as well. We used to recommend it as a substrate in FW tanks with Cichlids requiring higher pH levels…
A reactor is overkill… For sure… But mixing a kalk slurry for some calcium has merit, but like @vernal said, still need to add some magnesium then. I just get lazy and use epsom salts and my tap is high in calcium to begin with. I dont see a major need to use RO / RO/DI for the plants considering I am soil and my tap water is pretty good for the most part, just a little hard, but neutral pH.
Your reefkeeping knowledge will certainly give you a leg up with the garden. I used to farm corals myself, had over 1400 gallons at one time, including a 300g show reef. I was also a staff member on RC for a number of years and even worked on the beginnings of RK mag… Then I got divorced… Now I just scuba dive and have the biggest reef tank in the world instead LOL