That is huge ass pot tho. Gosh, 100 litres is sick haha
After I realized your watering pH level is in the safe zone and other elements deficiencies are not really showing I still don’t think it is pH level problem, but I am suspecting maybe too much EC in soil compare to plants at night time. I mean not lack root pressure is causing a problem.
So avoid watering few hrs prior to the night time or dilute the solution.
In my opinion, we can’t assure what causes the problem right now but we can start from higher chance and easier factor. (I’m saying higher chance by regulating irrigation, cuz you are aware of irrigation problem and aware that ur watering pH is at least right and there is no other symptoms than Ca deficiency.)